Yayınlanmış 1 Ocak 2017 | Sürüm v1

Diverse Modes of Reactivity of 6-(Chloromethyl)-6-methylfulvene

  • 1. San Francisco State Univ, Dept Chem & Biochem, 1600 Holloway Ave, San Francisco, CA 94132 USA
  • 2. Virginia Commonwealth Univ, Dept Chem, 1001 West Main St, Richmond, VA 23284 USA
  • 3. Uludag Univ, Dept Chem, TR-16059 Bursa, Turkey

Açıklama

The title compound exhibits a number of modes of reactivity toward nucleophiles/bases owing to the presence of several electrophilic and potentially nucleophilic sites in the molecule. We explored the reactions of 6-(chloromethyl)-6-methylfulvene with oxygen and nitrogen nucleophiles and bases as well as a carbon-based nucleophile (an enamine) and realized all possible reactivity modes predicted on the basis of electrophilic and nucleophilic positions in this compound.

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bib-eb23dff1-94e3-481f-879f-3fd9e558daf7.txt

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