Yayınlanmış 1 Ocak 2018
| Sürüm v1
Dergi makalesi
Açık
Synthesis of chiral tripodal receptors under solvent-free conditions using microwave irradiation for investigation of anion and cation recognition properties
Yazarlar/Oluşturanlar
- 1. Dicle Univ, Fac Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
Açıklama
Amide based chiral tripodal receptor derivatives were synthesized under microwave irradiation in quite high yields (76%- 84%) and they were characterized by IR and 1D, 2D, H-1- and C-13-NMR spectroscopies. The recognition properties of these tripodal receptors towards some anions and organic ammonium salts were investigated by H-1-NMR titration in DMSO-d(6). The tripodal (S)-phenyl receptor demonstrated a highly significant enantiomeric selectivity towards the (S)-(-)-1-phenyletylammonium perchlorate (ERF= 91.74 S).
Dosyalar
bib-3b1dfbdc-8a02-46dc-b6b3-ce9d07a064eb.txt
Dosyalar
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